In The Reactions       Two Isomers Of The Product Are Obtained. The Initial Complex Is

  1. Home
  2. JEE Main
  3. Chemistry
  4. Inorganic Chemistry
  5. Hydrogen and S block

Why Kaysons ?

Video lectures

Access over 500+ hours of video lectures 24*7, covering complete syllabus for JEE preparation.

Online Support

Practice over 30000+ questions starting from basic level to JEE advance level.

Live Doubt Clearing Session

Ask your doubts live everyday Join our live doubt clearing session conducted by our experts.

National Mock Tests

Give tests to analyze your progress and evaluate where you stand in terms of your JEE preparation.

Organized Learning

Proper planning to complete syllabus is the key to get a decent rank in JEE.

Test Series/Daily assignments

Give tests to analyze your progress and evaluate where you stand in terms of your JEE preparation.

SPEAK TO COUNSELLOR ? CLICK HERE

Download JEE Question paper & Solution Download JEE Important questions Download Complete syllabus of Maths, Physics, Chemistry

Question

 

In the reactions  

   

two isomers of the product are obtained. The initial complex is

Solution

Correct option is

Cis isomer

The initial complex must have two Cl– ions in cis position as the third Cl–ion could replace an ammonia cis to both or trans to one giving two isomers. If two Cl– ions were in the trans positions, the other four oppositions which could be replaced are equivalent and only one isomer of the product would be obtained. 

Download JEE Question paper & Solution Download JEE Important questions Download Complete syllabus of Maths, Physics, Chemistry

SIMILAR QUESTIONS

Q1

Octahedral complex of Ni (II) must be
medium View solution
Q2

Octahedral complex of Cr(III) will be
easy View solution
Q3

For the correct assignment of electronic configuration of a complex, the valence bond theory often requires the measurement of
easy View solution
Q4

Mn2+ forms a complex with Br– ion. The magnetic moment of the complex is 5.92 B.M. What would be the probable formula and geometry of the complex? 
easy View solution
Q5

How many isomers are possible for the complex ion [Cr(NH3)(OH)2Cl3]2–
easy View solution
Q6

A complex of certain metal has the magnetic moment of 4.91 BM whereas another complex of the same metal with same oxidation state has zero magnetic moment. The metal ion could be
medium View solution
Q7

The EAN of metal atoms in Fe(NO)2(CO)2 and Co2(CO)8 respectively are
easy View solution
Q8

The value of x in HxCr(CO)5 is
easy View solution
Q9

Following Sidwick’s rule of EAN, Co2(CO)x will be
easy View solution
Q10

On treatment of [Ni(NH3)4]2+ with concentrated HCl, two compounds I and II having the same formula, Ni(NH3)2Cl2 are obtained. I can be converted into II by boiling with dilute HCl. A solution of I reacts with oxalic acid to form [Ni(NH3)2(C2O4) whereas II does not react. Point out the correct statement of the following
medium View solution