0.92 G Of An Organic Compound Containing Carbon, Hydrogen And Oxygen Was analysed by Combustion Method. The Increase In Mass Of The U-tube And The Potash Bulbs At The End Of The Operation Was Found To Be 1.08 G And 1.76 G, Respectively. Determine The Percentage Composition Of The Compound. 

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Question

0.92 g of an organic compound containing carbon, hydrogen and oxygen was analysed by combustion method. The increase in mass of the U-tube and the potash bulbs at the end of the operation was found to be 1.08 g and 1.76 g, respectively. Determine the percentage composition of the compound. 

Solution

Correct option is

C = 52.17%; H = 13.04%, O = 34.79%.

 

Increase in mass of U-tube = 1.08 g  

Mass of water formed = 1.08 g 

Since, 18 g of water contain hydrogen = 2 g

1.08 g of water contain hydrogen   

Mass of compound taken for analysis = 0.92 g 

Percentage of hydrogen 

Increase in mass of potash bulbs = 1.76 g 

Mass of carbon dioxide formed = 1.76 g 

Since, 44 g of carbon dioxide contain carbon = 12 g   

1.76 g of carbon dioxide contain carbon   

Percentage of carbon 

                                    = 52.17. 

Percentage of oxygen = 100 – (per cent of C + per cent of H) 

                                    = 100 – (52.17 + 13.04) 

                                    = 100 – 65.21  

                                    = 34.79 

Composition of the compound : C = 52.17%; H = 13.04%, O = 34.79%.

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