Question

Solution

Correct option is

23.03%

20 ml dilute unreacted acid solution required 500 ml dilute unreacted acid solution required  = 80 ml N NaOH.

80 ml N NaOH 80 ml N H2SO4

Acid used for the neutralisation of NH3

= (100 – 80) ml N H2SO4

= 20 ml N H2SO4

Percentage of nitrogen N1 = 1, V = 20 ml and W = 1.216 g

So,  percentage of nitrogen, = 23.03%

SIMILAR QUESTIONS

Q1

0.92 g of an organic compound containing carbon, hydrogen and oxygen was analysed by combustion method. The increase in mass of the U-tube and the potash bulbs at the end of the operation was found to be 1.08 g and 1.76 g, respectively. Determine the percentage composition of the compound.

Q2

An organic substance (0.2115 g) on complete combustion gave 0.4655 g of carbon dioxide and 0.2533 g of water. Determine the percentage composition of the compound.

Q3

An organic compound was analysed by Duma’s method. 0.45 g of the compound on combustion gave 48.6 ml nitrogen at 27oC and 756 mm pressure. Calculate the percentage of nitrogen.

Q4

An organic compound on analysis gave the data : 0.25 g of the compound on complete combustion gave 0.37 g of CO2 and 0.2 g of water.

Q5

0.2 g of an organic compound was analysed by Kjeldahl’s method. Ammonia evolved was absorbed in 60 ml N/5 H2SO4. Unused acid required 40 ml of N/10 NaOH for complete neutralisation. Find the percentage of nitrogen in the compound.

Q6

0.5264 g silver bromide is obtained from 0.5124 g of an organic compound. Calculate the percentage of bromine in the compound.

Q7

0.156 g of an organic compound on heating with fuming HNO3 and AgNO3 gives 0.235 g of AgI. Calculate the percentage of the iodine in the compound.

Q8

0.1170 g of an organic compound on heating with conc. HNO3 and silver nitrate in Carius furnace gave 0.42 g of AgCl. Find the percentage of chlorine in the compound.

Q9

On heating 0.32 g of an organic compound with concentrated nitric acid and barium chloride, 0.932 g barium sulphate was obtained. Calculate the percentage of sulphur in the given compound.

Q10

6 g of an organic compound containing oxygen is heated with graphite and carbon monoxide formed is quantitatively converted to 8.8 g CO2 on reaction with I2O5. Calculate percentage of oxygen in the compound.