An Inorganic Compound (A) Gave The Following Reactions (i) The Compound On Heating Gave A Residue And A Gaseous Mixture Of NO2and O2. (ii) The Aqueous Solution Of (A) Gave A White Precipitate With Sodium Chloride Solution. The Precipitate Dissolves In NH4OH. The Compound (A) Is

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Question

 

An inorganic compound (A) gave the following reactions

(i) The compound on heating gave a residue and a gaseous mixture of NO2and O2.

(ii) The aqueous solution of (A) gave a white precipitate with sodium chloride solution. The precipitate dissolves in NH4OH. The compound (A) is

Solution

Correct option is

AgNO3

 

Since, the compound on heating gives a mixture of NO2 and O2, it must be a nitrate of a metal which is less reactive than Hg. (Ag is less reactive than Hg but Ba and Pb are more reactive than Hg). Moreover, the aqueous solution of the compound gives a white precipitate which is soluble in NH4OH. Thus, it is confirmed that the compound A is AgNO.

          The reactions are as follows

                           

                 

              

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